The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy+F / CF3O2 / MaricqSzente(1992)_295K_191-276nm(uncorr)

DATAFILE: CF3O2_MaricqSzente(1992)_295K_191-276nm(uncorr).txt
NAME: trifluoromethylperoxy radical
FORMULA: CF3O2
AUTHOR(YEAR): MaricqSzente(1992)
T: 295K
λ: 191-276nm(uncorr)
BIBLIOGRAPHY: M.M. Maricq and J.J. Szente, "Flash photolysis-time-resolved UV absorption study of the reactions CF3H + F → CF3 + HF and CF3O2 + CF3O2→ products", J. Phys. Chem. 96, 4925-4930 (1992); DOI: 10.1021/j100191a037
COMMENTS: Time-resolved ultraviolet spectroscopy has been used to measure the UV absorption spectrum of CF3O2 formed by the photodissociation of F2 in the presence of CF3H and O2

Spectrum uncorrected for FO2 presumably present in the reaction mixture

Absorption cross sections at 2.6-nm intervals as listed in Table 2

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